Inorganic Salts and Dehydrating Agents Cooperatively Promoted Ru-Catalyzed Ethylene Methoxycarbonylation Using CO2 as a CO Surrogate

Pd-catalyzed ethylene methoxycarbonylation with Brønsted acid ionic liquids as promoter and phase-separable reaction media†

Borate esters as alternative acid promoters in the palladium-catalyzed methoxycarbonylation of ethylene.

Co2(CO)8 Catalyzed Pauson–Khand Reaction under Microwave Irradiation1 Co2(CO)8 Catalyzed Pauson–Khand Reaction under Microwave Irradiation

Synlett 2002, No. 12, Print: 02 12 2002. Art Id.1437-2096,E;2002,0,12,2023,2026,ftx,en;G27602ST.pdf. © Georg Thieme Verlag Stuttgart · New York ISSN 0936-5214 Abstract: Microwave irradiation is used to accelerate Pauson– Khand reactions. The conditions for the Pauson–Khand reaction, catalytic in Co2(CO)8 under microwave irradiation, were optimized. It is possible to obtain various types of [2+2...

Arsenic, inorganic and soluble salts

Photoreduction of CO2 using [Ru(bpy)2(CO)L]n+ catalysts in biphasic solution/supercritical CO2 systems.

The reduction of CO2 in a biphasic liquid-condensed gas system was investigated as a function of the CO2 pressure. Using 1-benzyl-1,4-dihydronicotinamide (BNAH) as sacrificial electron donor dissolved in a dimethylformamide-water mixture and [Ru(bpy)2(CO)L](n+) as a catalyst and [Ru(bpy)3](2+) as a photosensitizer, the reaction was found to produce a mixture of CO and formate, in total about 25...